Modification of the integral isoconversional method to account for variation in the activation energy

By Sergery Vyazovkin. Journal of Computational Chemistry, 2001

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Isoconversional analysis of solid state transformations (2011, methodology): “Moreover, and in contrast to integral methods, differential and many other advanced methods can be applied to non-constant heating rate experiments [ 19 ] and non-Arrhenius temperature dependence of the rate constant [20, 21].”
Can nanoparticles really enhance thermal stability of polymers? Part I: An overview on thermal decomposition of addition polymers (2011, methodology): “The isoconversional method is in fact, a “model free” method which assumes that the conversion function f( ̨) does not change with the variation of the heating rate for all values of ̨ [91,92].”
ICTAC Kinetics Committee recommendations for performing kinetic computations on thermal analysis data (2011, methodology): “An example of such approach is integral isoconversionalmethodsdevelopedbyVyazovkin [24–26].”