Influence of slag chemistry on the hydration of alkali-activated blast-furnace slag — Part I: Effect of MgO
By Mohsen Ben Haha, B. Lothenbach, G. Saoût, F. Winnefeld. 2011
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The hydration and microstructural evolution of three alkali activated slags (AAS) with Al{sub 2}O{sub 3} contents between 7 and 17% wt.% have been investigated. The slags were hydrated in the presence of two different alkaline activators, NaOH and Na{sub 2}SiO{sub 3}{center_dot}5H{sub 2}O. The formation of C(-A)-S-H and hydrotalcite was observed in all samples by X-ray diffraction, thermal analysis and scanning electron microscopy. Higher Al{sub 2}O{sub 3} content of the slag decreased the Mg/Al ratio of hydrotalcite, increased the Al incorporation in the C(-A)-S-H and led to the formation of straetlingite. Increasing Al{sub 2}O{sub 3} content of the slag slowed down the early hydration and a lower compressive strength during the first days was observed. At 28 days and longer, no significant effects of slag Al{sub 2}O{sub 3} content on the degree of hydration, the volume of the hydrates, the coarse porosity or on the compressive strengths were observed.
Subfields: Civil and Structural Engineering, Materials Chemistry
View Paper: https://www.semanticscholar.org/paper/855ee5d93b22ef00dcd6439b850887cf4d14e1ba
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Citations in the corpus
- Reaction kinetics in sodium silicate powder and liquid activated slag binders evaluated using isothermal calorimetry (2012, background): “Similar calorimetric curves for NaOH activated slag pastes have been reported in [30,45].”