Covalent triazine-based frameworks (CTFs) from triptycene and fluorene motifs for CO2 adsorption

By S. Dey, A. Bhunia, D. Esquivel, C. Janiak. 2016

139 citations recorded by the source corpus.

Two microporous covalent triazine-based frameworks (CTFs) with triptycene (TPC) and fluorene (FL) backbones have been synthesized through a mild AlCl3-catalyzed Friedel–Crafts reaction, with the highest surface area of up to 1668 m2 g−1 for non-ionothermal CTFs. CTF-TPC and CTF-FL show an excellent carbon dioxide uptake capacity of up to 4.24 mmol g−1 at 273 K and 1 bar.

Subfields: Inorganic Chemistry, Materials Chemistry, Mechanical Engineering

View Paper: https://www.semanticscholar.org/paper/834858eccafa6014d67c9d50140fa915f3e9bd0a