Abuse behavior of high-power, lithium-ion cells

By R. Spotnitz, J. Franklin. 2003

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A Review of Lithium-Ion Battery Fire Suppression (2020, background): “This can lead to a loss of protection to the anode such that the fluorinated binder within the anode can react exothermically with lithiated carbon, exothermic reactions between the intercalated lithium and electrolyte, or cathode decomposition giving off oxygen enabling combustion with the electrol”
Pursuing safer batteries: Thermal abuse of LiFePO4 cells (2019, background): “ited to: (1) solid electrolyte interphase (SEI) reaction; (2) negative-solvent (NE) reaction; (3) positive-solvent (PE) reaction; (4) electrolyte decomposition (Richard and Dahn, 1999a,b; Spotnitz and Franklin, 2003; Melcher et al., 2016).”
Experimental Analysis of Thermal Runaway in 18650 Cylindrical Li-Ion Cells Using an Accelerating Rate Calorimeter (2016, result): “The heats of the reactions are in good agreement with the results from the literature [2,15] as are the activation energies [5].”