Quaternary Layered Ni-Rich NCMA Cathode for Lithium-Ion Batteries

By Un-Hyuck Kim, Liang-Yin Kuo, Payam Kaghazchi, Chong Seung Yoon, Yang‐Kook Sun. ACS Energy Letters, 2019

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Li[Ni1–x–yCoxAly]O2 (NCA) and Li[Ni1–x–yCoxMny]O2 (NCM) cathodes have been the archetypes of current high-energy-density cathodes for Li-ion batteries. A hybrid of NCA and NCM cathodes, a quaternary system consisting of Li[Ni0.89Co0.05Mn0.05Al0.01]O2 (NCMA) was benchmarked against NCM and NCA with similar Ni contents. The quaternary NCMA cathode delivered a capacity of 228 mAh g–1 and outperformed the benchmarking cathodes in long-term cycling stability (85% after 1000 cycles). The reduction in the volume change during deintercalation and the enhanced intrinsic mechanical strength confirmed by the single-particle compression test suppressed the microcrack nucleation and propagation. Microcrack suppression was important because microcracks serve as channels for electrolyte infiltration and lead to subsequent surface degradation of internal surfaces. The proposed NCMA cathode provides extra cycling stability, which is essential for electric vehicles, which require a long battery life and improves the therma...

Subfields: Automotive Engineering, Electrical and Electronic Engineering

View Paper: https://www.semanticscholar.org/paper/7c07c349f10b6ed1970f2cff60a5411ae22e0d6f

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