Chemistry as a probe of the structures and evolution of massive star-forming regions

By S. Doty, E. V. van Dishoeck, F. V. D. van der Tak, A. Boonman. 2002

133 citations recorded by the source corpus.

We present detailed thermal and gas-phase chemical models for the envelope of the massive star-forming region AFGL 2591. By considering both time- and space-dependent chemistry, these models are used to study both the physical structure proposed by van der Tak et al. (1999, 2000), as well as the chemical evolution of this region. The model predictions are compared with observed abundances and column densities for 29 species. The observational data cover a wide range of physical conditions within the source, but signicantly probe the inner regions where interesting high-temperature chemistry may be occurring. Taking appropriate care when comparing models with both emission and absorption measurements, we nd that the majority of the chemical structure can be well-explained. In particular, we nd that the nitrogen and hydrocarbon chemistry can be signicantly aected by temperature, with the possibility of high-temperature pathways to HCN. While we cannot determine the sulphur reservoir, the observations can be explained by models with the majority of the sulphur in CS in the cold gas, SO2 in the warm gas, and atomic sulphur in the warmest gas. Because the model overpredicts CO2 by a factor of 40, various high-temperature destruction mechanisms are explored, including impulsive heating events. The observed abundances of ions such as HCO + and N2H + and the cold gas-phase production of HCN constrain the cosmic-ray ionization rate to5:6 10 17 s 1 , to within a factor of three. Finally, we nd that the model and observations can simultaneously agree at a reasonable level and often to within a factor of three for 7 10 3 t(yrs) 5 10 4 , with a strong preference for t 3 10 4 yrs since the collapse and formation of the

Subfields: Astronomy and Astrophysics, Instrumentation, Statistical and Nonlinear Physics

View Paper: https://www.semanticscholar.org/paper/7be76f87ce7d4b362204845c6425ea66d3b17c92

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Citations in the corpus

Resetting chemical clocks of hot cores based on S-bearing molecules (2004, unknown): “In fact, it is more probable that hot cores have spatial gradients in temperature and density releasing the molecules at different times depending on their surface binding energies (see Ceccarelli et al. 1996; Viti & Williams 1999; Doty et al. 2002; Rodgers & Charnley 2003).”
Interstellar Turbulence II: Implications and Effects (2004, background): “For more recent work on chemistry covering a variety of applications not necessarily related to turbulence, see Roberts & Herbst (2002), Doty et al. (2002), Stantcheva & Herbst (2003), Shematovich et al. (2003), and Charnley & Markwick (2003).”
Molecular inventories and chemical evolution of low-mass protostellar envelopes (2003, background): “CS and SO are indeed found to show relatively small abundance variations in pure gas-phase models of pre-stellar cores (Bergin & Langer 1997) and in cold exterior regions of highmass protostellar envelopes (Doty et al. 2002).”
The Formation of Massive Stars from Turbulent Cores (2002, background): “Recently, Doty et al. (2002) have estimated the timescale for massive star formation using chemical clocks.”
Cosmic-ray ionization of molecular clouds (2009, background): “Over the past three decades, several values of ζH ranging from a few 10−17 s−1 to a few 10−16 s−1 have been obtained in diffuse interstellar clouds from measurements of the abundances of various chemical species, in particular OH (Black & Dalgarno 1977; Hartquist et al. 1978; Black et al. 1978) and ”