The reversibility of the reaction CaCO3 ⇄ CaO+CO2

By R. Barker. 2007

448 citations recorded by the source corpus.

Subfields: Biomaterials, Environmental Chemistry, Inorganic Chemistry

View Paper: https://www.semanticscholar.org/paper/79fac2f17b48644f6029178874c15fbf408236f0

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In Biomaterials

In Environmental Chemistry

In Inorganic Chemistry

Citations in the corpus

Multicycle activity of natural CaCO3 minerals for thermochemical energy storage in Concentrated Solar Power plants (2017, background): “The idea of integrating the CaL process into CSP plants for energy storage dates back to 21 the 1970s (Barker, 1973) (Barker, 1974) (Flamant et al.”
Reactivity of highly cycled particles of CaO in a carbonation/calcination loop (2008, background): “However, the results reviewed in previus works [2,5–9,11,12] and applied to many cycles in a recent aper presented by this group [10], showed that there is a simlarity in the decay trends of several limestones and that highly ycled samples present very similar pore structures.”
Limestone Calcination Nearby Equilibrium: Kinetics, CaO Crystal Structure, Sintering and Reactivity (2015, background): “Carbonation of CaO is initiated by a reaction-controlled 638 phase on the surface of the CaO grains until a thin layer of CaCO3 (between 30 and 50 639 nm thick [35, 63, 64]) is developed, which leads to a much slower phase driven by the 640 counter-current diffusion of inward CO2− 3 anion groups and”
Calcium-Looping performance of mechanically modified Al2O3-CaO composites for energy storage and CO2 capture (2018, background): “Many studies have evidenced that the CO2 uptake of a sorbent is enhanced by large surface area values [52, 65], albeit it is influenced also by the pore network and”
Carbon dioxide capture from combustion flue gases with a calcium oxide chemical loop. Experimental results and process development (2010, background): “…all free calcium oxide translates into rapid decay in the carbon dioxide capture capacity as the number of calcination-carbonation cycles increases (Barker, 1973; Curran, 1967), and this has been the subject of much concern about the viability of the reversible carbon dioxide capture process based…”