Do special noncovalent pi-pi stacking interactions really exist?
By Stefan Grimme. Angewandte Chemie, 2008
958 citations recorded by the source corpus.
Subfields: Atomic and Molecular Physics, and Optics, Materials Chemistry, Physical and Theoretical Chemistry
View Paper: https://www.semanticscholar.org/paper/7953cc0bb53671d0ab56cb902ae488452ef2d9b7
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In Atomic and Molecular Physics, and Optics
In Materials Chemistry
In Physical and Theoretical Chemistry
Citations in the corpus
- A simple method of identifying π orbitals for non-planar systems and a protocol of studying π electronic structure (2020, background): “For example, the nature of aromaticity and accompanied unique features of organic molecules stem from large range delocalization of π electrons; [1–3] the n → π* and π → π* types of electron transitions bring color for organic dyes; [4] the π–π stacking interaction essentially results from electron ”
- Independent gradient model based on Hirshfeld partition: A new method for visual study of interactions in chemical systems (2021, background): “As indicated by the pink arrows, some areas on the isosurfaces show deep blue color, as if there are strong attractive interactions, which in fact are artificial, since it is well known that the - stacking interaction between two six-membered aromatic rings is fairly weak.[58] Obviously, this prob”