Optimization of CH3NH3PbI3 perovskite solar cells: A theoretical and experimental study

By Isaac Montoya De Los Santos, H. J. Cortina-Marrero, M. A. Ruiz-Sánchez, L. Hechavarría-Difur, F. Sánchez-Rodríguez, M. Courel, Hailing Hu. 2020

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Abstract In this work, an experimental and theoretical study on CH3NH3PbI3 perovskite solar cells was performed. A theoretical validation of experimental results in perovskite solar cells with efficiencies of 13.32% is presented. An optimization study which involves the spiro-OMeTAD and perovskite thickness’ influence on electrical output parameters (Voc, Jsc, FF and PCE) showed a promotion of solar cell efficiency to 15.50% under 100 nm and 400 nm for hole transport material and absorber, respectively. The importance of the diffusion length of the absorber is discussed. In order to enhance the efficiency, a study of defect density (NT) was applied at the range of 1016 cm−3 (experimental) to 1010 cm−3 (theoretical) where we achieved an efficiency of 20.26%. The present work illustrates the importance of thickness optimization and the reduction of defect density (by the improvement of the quality of processed film) to obtain a better performance of this type of solar cell. Furthermore, the relevance of the implementation of a back contact with higher work function was studied.

Subfields: Electrical and Electronic Engineering, Materials Chemistry

View Paper: https://www.semanticscholar.org/paper/76311710c2532d18e337af08ce3b942e16f87eae