Ion sieving effects in the electrical double layer of porous carbon electrodes: Estimating effective ion size in electrolytic solutions

By Linoam Eliad, G. Salitra, A. Soffer, D. Aurbach. 2001

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Recent advances in ion selectivity with capacitive deionization (2021, methodology): “…et al. showed a high selectivity for nitrate over chloride and sulfate by using ultra-microporous (pore diameter o 1 nm) carbon electrodes.41 The idea is similar to the one already explored by Eliad et al. (2001), in which selectivity is achieved due to sieving effect of very small carbon pores.”
Effect of pore texture on performance of activated carbon supercapacitor electrodes derived from olive pits (2015, neutral): “421 nm [19].”
Reviewing the fundamentals of supercapacitors and the difficulties involving the analysis of the electrochemical findings obtained for porous electrode materials (2020, background): “Then, considering the original work of Aurbach et al. [182], the discovery of a different, more ef ﬁ cient charge-storage mechanism in sub-nanometer micropores ( d p < 1.0 nm), led to a change in the current opinion of the scienti ﬁ c community, i.e., not only the surface but also [183] the pore…”