CVD synthesis of high-purity multiwalled carbon nanotubes using CaCO3 catalyst support for large-scale production

By E. Couteau, K. Hernádi, J. Seo, L. Thiên-Nga, C. Mikó, R. Gaal, L. Forró. 2003

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An Overview of the Recent Progress in the Synthesis and Applications of Carbon Nanotubes (2019, background): “, powder [44] and the aligned forest of the CNTs [45,46].”
Mass production of high-quality multi-walled carbon nanotube bundles on a Ni/Mo/MgO catalyst (2005, methodology): “Large-scale synthesis of CNTs has been developed in recent years [15–18].”
Carbon Nanotube Synthesis via the Catalytic CVD Method: A Review on the Effect of Reaction Parameters (2006, background): “Widely used catalyst materials in carbon nanotube synthesis are cobalt (32, 44, 45), iron (32, 46, 47), titanium (47), nickel (3, 48), a couple of zeolites and combinations of these metals and/or oxides (3, 49, 50, 51).”
Effect of Thermal Treatment on the Structure of Multi-walled Carbon Nanotubes (2006, methodology): “…to produce MWCNTs such as alcohol CCVD with a cold wall (Chiashi et al., 2004); thermal CVD with metal catalysts of nickel, cobalt and iron (Lee et al., 2001, 2002); and ceramic catalysts of Fe3O4 (Kobayashi et al., 2004), MgO (Ago et al., 2004), CaCO3, Co/CaCO3 and Fe/CaCO3 (Couteau et al., 2003).”