Coal-based S hybrid self-doped porous carbon for high-performance supercapacitors and potassium-ion batteries

By Qing Wang, Shao‐hua Luo, Zhang Yahui, Xin Liu, Yanguo Liu, Zhi-Yuan Wang, Hao Aimin, Tingfeng Yi. Journal of Power Sources, 2020

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Abstract A hybrid composed of sulfur self-doped 3D hierarchical porous carbon (S-3DHPC) with a high defect density area and a high specific surface is prepared through direct carbonization of coal and activators without any additional template. The synthesized S-3DHPC is directly used as an electrode for supercapacitors and potassium ion batteries. The large surface area of the three-dimensional carbon network allowed full contact of the electrolyte with the electrode interface, and the transport path of the electrolyte ions and K+ is shorter. In addition, S-type doping in hierarchical porous carbon improves the electronic conductivity and provides superior electrochemical performance. The S-3DHPC electrode with 431.7 F g−1 at 1 A g−1 in a 3 M KOH electrolyte demonstrates an adequate rate performance and cycle stability. In particular, the assembled S-3DHPC-based flexible symmetric supercapacitor exhibits a high energy density of 17.8 Wh kg−1 at a power density of 652 W kg−1. Furthermore, S-3DHPC as the anode for K-ion batteries exhibits a high reversible capacity of 212.9 mAh g−1 at 50 mA g−1, an excellent rate capability, and outstanding cycling performance. Therefore, S-3DHPC has broad application prospects as a high-performance energy storage electrode material.

Subfields: Electrical and Electronic Engineering, Electronic, Optical and Magnetic Materials

View Paper: https://www.semanticscholar.org/paper/6e76ac82a52e4d72b7efd89ed1197bfb3171b6a0