Distortion/interaction energy control of 1,3-dipolar cycloaddition reactivity.

By D. Ess, K. Houk. Journal of the American Chemical Society, 2007

788 citations recorded by the source corpus.

Subfields: Electrical and Electronic Engineering, Organic Chemistry

View Paper: https://www.semanticscholar.org/paper/6cc42a2bfbce412248cd520ddaaa6df238a37ffb

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Citations in the corpus

• The Baldwin rules: revised and extended (2016, background): “In addition to the stabilizing two-electron bondforming interactions, one should also consider the destabilizing effects associated with the deformation of acyclic reagents from their ideal geometries needed in order to reach the TS.118 The energy cost for deviations from a reactive center’s ideal g”