Breakdown of the adiabatic Born-Oppenheimer approximation in graphene.

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Catalyst-free growth of nanographene films on various substrates (2011, background): “Graphene has attracted much attention owing to its unique structure [1, 2], interesting properties [1, 3–5], and promising device applications [1, 6, 7].”
Raman characterization of defects and dopants in graphene (2015, background): “However, as the electron–phonon coupling increases the electrons no longer fully relax to their ground states during the lattice vibrations and therefore they no longer move adiabatically with the ions, which reduces the phonon energy [30, 31].”
Unusual infrared-absorption mechanism in thermally reduced graphene oxide. (2010, neutral): “and deviation from the adiabatic Born–Oppenheimer approximatio”
Production, properties and potential of graphene (2010, background): “[163] Pisana S, Lazzeri M, Casiraghi C, Novoselov KS, Geim AK, Ferrari AC, et al.”