The Iron Oxides: Structure, Properties, Reactions, Occurrences and Uses

By R. M. Cornell, U. Schwertmann. 2003

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Biotransformation of two-line silica-ferrihydrite by a dissimilatory Fe(III)-reducing bacterium: Formation of carbonate green rust in the presence of phosphate (2004, background): “Such stability was expected because Si and P retard ferrihydrite crystallization (Kandori et al., 1992; Cornell and Schwertmann, 1996).”
Increasing Iron Availability to Crops: Fertilizers, Organo-Fertilizers, and Biological Approaches (2005, background): “The stability constant of this reaction depends on the hydroxide type of mineral and its degree of erystallization, and it ranges between 37, for poorly crystallized ferrihydrite, to 44 or even 46, for well-crystallized goethite (Schwertmann and Taylor 1977; Trolard and Trady 1987; Cornell and Schwe”
Characteristics of Phosphate Adsorption-Desorption Onto Ferrihydrite: Comparison With Well-Crystalline Fe (Hydr)Oxides (2013, methodology): “Hematite formed under different conditions displays different sets of planes, and these in turn exhibit different sets of functional groups (Cornell and Schwertmann, 2003).”