One-step synthesis of novel Fe3C@nitrogen-doped carbon nanotubes/graphene nanosheets for catalytic degradation of Bisphenol A in the presence of peroxymonosulfate

By Wenjie Ma, Na Wang, Yunchen Du, Tianze Tong, Leijiang Zhang, Kun-Yi Andrew Lin, Xi-jiang Han. Chemical Engineering Journal, 2019

195 citations recorded by the source corpus.

Abstract Developing novel carbocatalysts with available strategies for peroxymonosulfate (PMS) activation has become a popular topic in environmental remediation and protection fields. Herein, using commercial K4Fe(CN)6 as the precursor, Fe3C@nitrogen-doped carbon nanotubes/graphene nanosheets (Fe3C@NCNTs/GNS) is synthesized by a direct high-temperature pyrolysis. Characterization results prove that Fe3C@NCNTs/GNS has a relatively high graphitization degree and rich nitrogen doping content, which endow it with excellent catalytic efficiency in PMS activation for powerful removal of Bisphenol A (BPA). Influences of catalyst/oxidant dosages, some inorganic anions, humic acid, and practical sewages are investigated in detail. For mechanism studies, it is found that tert-butyl alcohol (TBA)/methanol fails to inhibit BPA degradation, and the primary reactive oxidative species (ROS) are superoxide radical (O2 −) and singlet oxygen (1O2). Discussion on the origin of 1O2 confirms that moderate modification of N atoms in graphitic carbon frameworks plays an essential role in inducing the non-radical mechanism. This work will provide new insights for the preparation of high-performance carbocatalysts in PMS activation and exploring critical roles of N-doping during non-radical processes.

Subfields: Biomedical Engineering, Renewable Energy, Sustainability and the Environment, Water Science and Technology

View Paper: https://www.semanticscholar.org/paper/65888f2d91a44029a8dba094c7d81d5bdfc2ce8d