A fully biobased epoxy resin from vegetable oils: From the synthesis of the precursors by thiol‐ene reaction to the study of the final material

By M. Stemmelen, Freddy Pessel, V. Lapinte, S. Caillol, J. Habas, J. Robin. 2011

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The thiol‐ene (click) reaction for the synthesis of plant oil derived polymers (2013, methodology): “In order to get both components renewable, a polyamine was prepared from grapeseed oil via thiol-ene addition of cysteamine chloride and cross-linked with epoxidized linseed oil [47].”
A Review of Recent Research on Bio-Based Epoxy Systems for Engineering Applications and Potentialities in the Aviation Sector (2018, background): “[43], developed a novel vegetable oil-based polyamine from grapeseed oil (AGSO) through thiol-ene coupling reaction.”
The use of renewable feedstock in UV-curable materials - A new age for polymers and green chemistry (2013, background): “Otherwise, various chemical pathways to functionalize triglycerides and fatty acids, such as hydroformylation [3,4], thiol-ene reaction (TEC) [5,6] and selective oxidation [7] have already been described.”
Wood products and green chemistry (2016, background): “…used for wood due to their high price, nonetheless it is of interest that epoxy resins derived from wood and bark-derived natural materials have been developed (Nouailhas et al. 2011; Aouf et al. 2013) in competition with biobased epoxy resins obtained from vegetable oils (Stemmelen et al. 2011).”
Synthesis and Modifications of Epoxy Resins and Their Composites: A Review (2014, background): “Stemmelen et al.[68] synthesized a novel vegetable oil-based polyamine from grapeseed oil (GSO).”