Decomposition of Austenite in Austenitic Stainless Steels
By A. F. Padilha, P. R. Rios. 2002
460 citations recorded by the source corpus.
Austenitic stainless steels are probably the most important class of corrosion resistant metallic materials. In order to attain their good corrosion properties they rely essentially on two factors: a high chromium content that is responsible for the protective oxide film layer and a high nickel content that is responsible for the steel to remain austenitic. Thus the base composition is normally a Fe-Cr-Ni alloy. In practice the situation is much more complex with several other elements being present, such as, Mo, Mn, C, N among others. In such a complex situation one almost never has a single austenite phase but other phases invariably form. Those phases are, with few exceptions, undesirable and they can be detrimental to the corrosion and mechanical properties. It is therefore of considerable importance to study the formation of such phases. In this work the decomposition of austenite in austenitic stainless steels is reviewed in detail. First the binary equilibrium diagrams relevant to the system Fe-Cr-Ni are briefly presented as well as other diagrams, such as the Schaeffler diagram, that traditionally have been used to predict the phases present in these steels as a function of composition. Secondly the precipitation of carbides and intermetallic phases is presented in detail including nucleation sites and orientation relationships and the influence of several factors such as composition, previous deformation and solution annealing temperature. Next, the occurrence of other constituents such as nitrides, sulfides and borides is discussed. TTT diagrams are also briefly presented. Finally the formation of martensite in these steels is discussed.
Subfields: Mechanical Engineering, Mechanics of Materials, Metals and Alloys
View Paper: https://www.semanticscholar.org/paper/6489b992a890f8f1db9da7af27f08faf661c5569
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In Mechanical Engineering
In Metals and Alloys
Citations in the corpus
- Overview of Intermetallic Sigma () Phase Precipitation in Stainless Steels (2012, background): “Padilha and Rios [22] pointed out that the σ phase precipitating directly in γaustenite was very slow (about several thousand hours) [23].”