Study of vanadium-based chemical conversion coating on the corrosion resistance of magnesium alloy

By K. H. Yang, M. Ger, W. Hwu, Y. Sung, Y. Liu. 2007

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Review of electrochemical properties of hybrid coating systems on Mg with plasma electrolytic oxidation process as pretreatment (2019, background): “Although molybdenum (VI) is used as a localized corrosion inhibitor and alloying element in steel, it produces a thin conversion coating and shows poor adhesion to the substrate [109,110].”
Alternative conversion coatings to chromate for the protection of magnesium alloys (2014, background): “permanganate with HNO3 [20], (e) permanganate with HF [20], (f) permanganate with HCl [20], (g) phosphate permanganate [37], (h) cerium [38], (i) Lanthanum [39] and (j) vanadium [40].”
Formation of Mg,Al-hydrotalcite conversion coating on Mg alloy in aqueous HCO3−/CO32− and corresponding protection against corrosion by the coating (2009, background): “Several promising chromate-free conversion coatings of Mg alloys, including phosphate [22–25], phosphate–permanganate [26,27], stannate [27–31], vanadate [32], cobalt-III hex coordinated complex [33], cerate [34–37] or lanthanite [35] or praseodymate [35] and other coatings have been studied.”
Comprehensive screening of Mg corrosion inhibitors (2017, unknown): “NaVO3 0,05M 9,8* 90 -6 4 -360 -58 -9 -167 [51, 52]”