Comparison of far-from-equilibrium work relations

By Christopher Jarzynski. 2006

148 citations recorded by the source corpus.

Abstract Recent theoretical predictions and experimental measurements have demonstrated that equilibrium free energy differences can be obtained from exponential averages of nonequilibrium work values. These results are similar in structure, but not equivalent, to predictions derived nearly three decades ago by Bochkov and Kuzovlev, which are also formulated in terms of exponential averages but do not involve free energy differences. In the present article the relationship between these two sets of results is elucidated, then illustrated with an undergraduate-level solvable model. The analysis also serves to clarify the physical interpretation of different definitions of work that have been used in the context of thermodynamic systems driven away from equilibrium. To cite this article: C. Jarzynski, C. R. Physique 8 (2007).

Subfields: Biomedical Engineering, Mechanical Engineering, Statistical and Nonlinear Physics

View Paper: https://www.semanticscholar.org/paper/60c83cf49aadc0bab4b00a5f27f34b3ca3c50164

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In Biomedical Engineering

  1. U. Seifert
  2. Andrea Puglisi
  3. Michele Campisi
  4. P. Talkner
  5. Christian Maes
  6. Fabio Marchesoni
  7. Jordan M. Horowitz
  8. Angelo Vulpiani

In Mechanical Engineering

  1. Michele Campisi
  2. P. Talkner
  3. Christian Maes
  4. Fabio Marchesoni
  5. Jordan M. Horowitz
  6. Massimiliano Esposito
  7. P. Hänggi
  8. U. Seifert

In Statistical and Nonlinear Physics

  1. Jordan M. Horowitz
  2. P. Hänggi
  3. U. Seifert
  4. Massimiliano Esposito
  5. P. Talkner
  6. Christian Maes
  7. Andrea Puglisi
  8. Angelo Vulpiani

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