Ion-exchange behavior of carboxylate groups in fibrous cellulose oxidized by the TEMPO-mediated system

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A critical review of cellulose-based nanomaterials for water purification in industrial processes (2018, methodology): “In recent literature, the standard surface area of cellulose pulp was increased from 4 m2/g to over 500 m2/g by conversion into cellulose nanopaper using preparation methods, such as mechanical mixing, treatment with enzymes, and electrospinning (Banavath et al. 2011; Sehaqui et al. 2011, 2014).”
A review on modification methods to cellulose-based adsorbents to improve adsorption capacity. (2016, methodology): “…groups in 2,2,6,6-tetramethylpiperidine-1oxy radical (TEMPO)-oxidized fibrous cellulose prepared from cotton linters was compared with that of fibrous carboxymethyl cellulose (F-CMC) with almost the same carboxylate content as that of the TEMPO-oxidized cellulose (Saito and Isogai, 2005).”
Enhancing adsorption of heavy metal ions onto biobased nanofibers from waste pulp residues for application in wastewater treatment (2014, background): “In a study by Saito et al., the capacity of TEMPOoxidized cellulosic fibers to adsorb a wide range of metal ions was demonstrated (Saito and Isogai 2005).”
Microfibrillated cellulose and new nanocomposite materials: a review (2010, background): “On the other hand, when native celluloses are used, the initial fibrous morphology is mostly maintained, even after the TEMPO-mediated oxidation under harsh conditions (Saito and Isogai 2005).”