Improved Cyclability of Liquid Electrolyte Lithium/Sulfur Batteries by Optimizing Electrolyte/Sulfur Ratio

By Shengbo Zhang. 2012

196 citations recorded by the source corpus.

A liquid electrolyte lithium/sulfur (Li/S) cell is a liquid electrochemical system. In discharge, sulfur is first reduced to highly soluble Li 2 S 8 , which dissolves into the organic electrolyte and serves as the liquid cathode. In solution, lithium polysulfide (PS) undergoes a series of complicated disproportionations, whose chemical equilibriums vary with the PS concentration and affect the cell’s performance. Since the PS concentration relates to a certain electrolyte/sulfur (E/S) ratio, there is an optimized E/S ratio for the cyclability of each Li/S cell system. In this work, we study the optimized E/S ratio by measuring the cycling performance of Li/S cells, and propose an empirical method for determination of the optimized E/S ratio. By employing an electrolyte of 0.25 m LiSO 3 CF 3 -0.25 m LiNO 3 dissolved in a 1:1 (wt:wt) mixture of dimethyl ether (DME) and 1,3-dioxolane (DOL) in an optimized E/S ratio, we show that the Li/S cell with a cathode containing 72% sulfur and 2 mg cm − 2 sulfur loading is able to retain a specific capacity of 780 mAh g −1 after 100 cycles at 0.5 mA cm −2 between 1.7 V and 2.8 V.

Subfields: Automotive Engineering, Electrical and Electronic Engineering

View Paper: https://www.semanticscholar.org/paper/5afe0651feb8666d75b00115ffd849776672ef15