Homogeneous suspensions of individualized microfibrils from TEMPO-catalyzed oxidation of native cellulose.

By Tsuguyuki Saito, Y. Nishiyama, J. Putaux, M. Vignon, A. Isogai. Biomacromolecules, 2006

1,617 citations recorded by the source corpus.

Subfields: Biomaterials, Biomedical Engineering, Building and Construction

View Paper: https://www.semanticscholar.org/paper/5ad425dcc83ac952ddc4be720f4eb821eb9f77de

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Citations in the corpus

Processing of wood-based microfibrillated cellulose and nanofibrillated cellulose, and applications relating to papermaking: a review (2016, background): “The main effect of TEMPO on cellulose is to selectively oxidise C6 hydroxyl groups into carboxyl groups and partially aldehydes on the surface of cellulose fibril (Carlsson et al. 2015; Saito et al. 2006, 2007).”
Mechanical and thermal properties of waterborne epoxy composites containing cellulose nanocrystals (2013, background): “CNCs are isolated from bulk cellulose by mechanical or chemical treatment to separate amorphous from crystalline regions, including acid hydrolysis [1e3], oxidation (for example, the TEMPO-mediated oxidation process) [4], homogenization [5,6], and grinding [7].”
The behaviour of cationic NanoFibrillar Cellulose in aqueous media (2011, background): “So far the unmodified (Pa ¨a ¨kko ¨ et al. 2007) and anionically modified nanofibrils ( Saito et al. 2006, 2007 ; W agberg et al. 1987, 2008) have gained most attention in the literature.”
A new bio-based nanocomposite: fibrillated TEMPO-oxidized celluloses in hydroxypropylcellulose matrix (2009, background): “This is well within the oxidation range (0.99‐1.23 mmol/g) earlier reported for effective disintegration ( Saito et al. 2006 ).”
An environmentally friendly method for enzyme-assisted preparation of microfibrillated cellulose (MFC) nanofibers (2007, methodology): “However, MFC nanofibers were recently disintegrated in a more efficient process where 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) oxidation was utilized as a pretreatment step prior to mechanical treatment [10].”
Preparation and characterization of sterically stabilized nanocrystalline cellulose obtained by periodate oxidation of cellulose fibers (2015, methodology): “Individual nanofibrils cellulose (NFC) with 5 nm in width and at least 2 lm in length were produced by a 2,2,6,6-tetramethylpiperidine-1oxyl (TEMPO)-mediated oxidation pretreatment on cellulose before mechanical treatment (Saito et al. 2006; Fukuzumi et al. 2009).”