Oxidative coupling of aromatic substrates with alkynes and alkenes under rhodium catalysis.
By T. Satoh, M. Miura. Chemistry, 2010
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Aromatic substrates with oxygen- and nitrogen-containing substituents undergo oxidative coupling with alkynes and alkenes under rhodium catalysis through regioselective C-H bond cleavage. Coordination of the substituents to the rhodium center is the key to activate the C-H bonds effectively. Various fused-ring systems can be constructed through these reactions.
Subfields: Organic Chemistry
View Paper: https://www.semanticscholar.org/paper/54911b03cf78ddd8c773f6ec05cd06121b9019fd
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In Organic Chemistry
Citations in the corpus
- Rhodium(III)-catalyzed heterocycle synthesis using an internal oxidant: improved reactivity and mechanistic studies. (2011, background): “2011, 133, 6449–6457 In recent elegant reports, Satoh and Miura,10 Glorius,11,12 and Bergman and Ellman13 independently demonstrated that using alkenes under very similar conditions resulted in oxidative olefination reaction.14 These reactions demonstrate the capability of Rh(III) catalysts to…”