Acrolein: sources, metabolism, and biomolecular interactions relevant to human health and disease.

By J. F. Stevens, C. Maier. Molecular Nutrition & Food Research, 2008

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Vitamins C and E: Beneficial effects from a mechanistic perspective (2011, background): “The reaction of ascorbate with acrolein (2-propenal), a ubiquitous electrophile originating from LPO and combustion of organic matter [123], and with other α,β-unsaturated aldehydes/ketones has been reported in the organic chemistry literature [121,124].”
Metabolomics for Investigating Physiological and Pathophysiological Processes. (2019, background): “These adducts ultimately lead to protein deactivation which affects many organ systems (329, 445).”
Role of Lactobacillus reuteri in Human Health and Diseases (2018, background): “Moreover, the antimicrobial activity of reuterin seems to rely on the spontaneous conversion of 3-HPA to acrolein, a cytotoxic electrophile (Stevens and Maier, 2008; Engels et al., 2016).”