A Directional Synthesis for Topological Defect in Carbon

By Xin Wang, Y. Jia, X. Mao, Longzhou Zhang, Daobin Liu, Li Song, Xuecheng Yan, Jun Chen, Dongjiang Yang, Jizhi Zhou and 3 more. Chem, 2020

191 citations recorded by the source corpus.

Recently, defect electrocatalysis has become a research focus with significant advances. However, the control synthesis of target defects is still challenging to date, which is prerequisite for deeply understanding the intrinsic activity origin of metal-free catalysts. Herein, inspired by the theoretical demonstration, we report a general edge-engineering strategy to fulfill controlling definitive defect configurations in carbons by the direct removal of specific nitrogen (N) doping sites, representing as one-to-one conversion; e.g., graphitic-N to divacancy (C585), pyridinic-N to separate pentagon (S-C5), and pyrrolic-N to adjacent pentagons (A-C5). Electrochemical measurements reveal that A-C5 defects prefer oxygen reduction reaction (ORR) catalysis, whereas C585 defects are more favorable toward hydrogen evolution reaction (HER). This work provides insights into the design of high-performance carbon-based catalysts based on the principles of defect formation.

Subfields: Electrical and Electronic Engineering, Renewable Energy, Sustainability and the Environment

View Paper: https://www.semanticscholar.org/paper/53275eee3b8c7d51eb7e1cc1864b5cdab62f2610