Formation of Magnesium Dendrites during Electrodeposition

By Rachel D. Davidson, A. Verma, David A. Santos, Feng Hao, C. Fincher, Sisi Xiang, Jonathan S. Van Buskirk, K. Xie, M. Pharr, Partha P. Mukherjee and 1 more. ACS Energy Letters, 2019

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We demonstrate the growth of dendritic magnesium deposits with fractal morphologies exhibiting shear moduli in excess of values for polymeric separators upon the galvanostatic electrodeposition of metallic Mg from Grignard reagents in symmetric Mg–Mg cells. Dendritic growth is understood on the basis of the competing influences of reaction rate, electrolyte transport rate, and self-diffusion barrier.

Subfields: Condensed Matter Physics, Electrical and Electronic Engineering, Electronic, Optical and Magnetic Materials

View Paper: https://www.semanticscholar.org/paper/4d80d76c297df4066dfd345a9ead22212a45bd9c

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