Stability of nanostructured iridium oxide electrocatalysts during oxygen evolution reaction in acidic environment

By S. Cherevko, T. Reier, Aleksandar R. Zeradjanin, Zarina Pawolek, P. Strasser, K. Mayrhofer. 2014

273 citations recorded by the source corpus.

The electrochemical stability of thermally prepared Ir oxide films is investigated using a scanning flow cell (SFC)–inductively coupled plasma mass-spectrometer (ICP-MS) setup under transient and stationary potential and/or current conditions. Time-resolved dissolution rates provide important insights into critical conditions for material breakdown and a fully quantitative in-situ assessment of the electrochemical stability during oxygen evolution reaction (OER) conditions. In particular, the results demonstrate that stability and OER activity of the IrOx catalysts strongly depend on the chemical and structural nature of Ir oxide species and their synthesis conditions.

Subfields: Electrical and Electronic Engineering, Renewable Energy, Sustainability and the Environment

View Paper: https://www.semanticscholar.org/paper/4b6775b0fcf4f74c6cdce872dc210f8899c42c64