Predominant Intermediate-Spin Ferrous Iron in Lowermost Mantle Post-Perovskite and Perovskite

By Jung-Fu Lin, H. Watson, G. Vankó, E. Alp, V. Prakapenka, Przemek Dera, V. Struzhkin, Atsushi Kubo, Jiyong Zhao, C. McCammon and 1 more. 2008

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Inelastic x-ray scattering by electronic excitations under high pressure (2008, background): “This interpretation however contrasts with the more recent XES results of Lin et al. (2008) in (Mg0.”
LLNL‐G3Dv3: Global P wave tomography model for improved regional and teleseismic travel time prediction (2012, background): “…to purely compositional origins for the muting of P wave velocities in the ancient slab structures [see Badro et al., 2003, 2004; Hofmeister, 2006; Lin et al., 2007, 2008; Speziale et al., 2007; Stackhouse et al., 2007;McCammon et al., 2008; Crowhurst et al., 2008; Wentzcovitch et al., 2009;…”
Spin state of ferric iron in MgSiO3 perovskite and its effect on elastic properties (2010, background): “et al. (2008) and Lin et al. (2008) observed an unusually high quadrupole splitting for Fe2+ and intermediate satellite peak intensity in XES, proposing a transition of Fe2+ from HS to intermediate spin.”
GyPSuM: A joint tomographic model of mantle density and seismic wave speeds (2010, background): “…but the actual effects that electronic spin transitions have on mantle materials is still uncertain [see Badro et al. 2003, 2004; Hofmeister 2006; Lin et al. 2007, 2008; Speziale et al. 2007; Stackhouse et al. 2007; McCammon et al. 2008; Crowhurst et al. 2009; Wentzcovitch et al. 2009].”