Redefining the Robeson upper bounds for CO2/CH4 and CO2/N2 separations using a series of ultrapermeable benzotriptycene-based polymers of intrinsic microporosity

By Bibiana Comesaña-Gándara, Jie Chen, C. Bezzu, M. Carta, I. Rose, M. Ferrari, E. Esposito, A. Fuoco, Johannes Carolus Jansen, Neil B. McKeown. Energy & Environmental Science, 2019

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Ultrapermeable benzotriptycene-based PIMs show exceptional gas selectivities that define new positions for the CO2/CH4 and CO2/N2 Robeson upper bounds.

Subfields: Inorganic Chemistry, Materials Chemistry, Mechanical Engineering

View Paper: https://www.semanticscholar.org/paper/400b22b7ce6e119ead856c512f5ce01f3438f6db