Designing Low Impedance Interface Films Simultaneously on Anode and Cathode for High Energy Batteries

By Bo Liao, Hongying Li, Mengqing Xu, L. Xing, Youhao Liao, Xiubin Ren, W. Fan, Le Yu, Kang Xu, Weishan Li. Advanced Energy Materials, 2018

233 citations recorded by the source corpus.

High energy batteries urgently required to power electric vehicles are restricted by a number of challenges, one of which is the sluggish kinetics of cell reactions under low temperatures. A novel approach is reported to improve the low temperature performance of high energy batteries through rational construction of low impedance anode and cathode interface films. Such films are simultaneously formed on both electrodes via the reduction and oxidation of a salt, lithium difluorobis(oxalato) phosphate. The formation mechanisms of these interface films and their contributions to the improved low temperature performances of high energy batteries are demonstrated using various physical and electrochemical techniques on a graphite/LiNi0.5Co0.2Mn0.3O2 battery using 1 m LiPF6‐ethylene carbonate/ethyl methyl carbonate (1/2, in weight) baseline electrolyte. It is found that the interface impedances, especially the one on the anode, constitute the main obstacle to capacity delivery of high energy batteries at low temperatures, while the salt containing fluorine and oxalate substructures used as additives can effectively suppress them.

Subfields: Automotive Engineering, Electrical and Electronic Engineering

View Paper: https://www.semanticscholar.org/paper/3ea076b4d3bbf3d4a030b0fadbce9a3d0875b1ea