Surface-initiated atom transfer radical polymerization of methyl methacrylate on magnetite nanoparticles

By Eizo Marutani, S. Yamamoto, Tsedev Ninjbadgar, Y. Tsujii, T. Fukuda, M. Takano. 2004

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CuO nanoparticle filled vinyl-ester resin nanocomposites: Fabrication, characterization and property analysis (2007, methodology): “, by dispersing the synthesized nanoparticles into an organic polymeric solution [13–16] and in situ monomer polymerization methods in the presence of the nanoparticles [17–21] have been reported for polymeric composite fabrication.”
Responsive Polymers in Biology and Technology (2011, methodology): “68 applied the copper-mediated ATRP technique to graft polymerization of methyl methacrylate (MMA) on magnetite (Fe 3 O 4 ) nanoparticles with an ATRP initiator, 2-(4-chlorosulfonylphenyl) ethyl trichlorosilane (CTCS), immobilized on their surfaces ( Fig.”
Nanocomposite Materials from Functional Polymers and Magnetic Colloids (2007, methodology): “193 194 Colloidal initiators were synthesized by the attachment of 2‐(4‐chlorosulfonylphenyl)ethyltrichlorosilane to the oxide surface of both γ‐Fe 2 O 3 and Fe 3 O 4 .”
Polymer brush synthesis on surface modified carbon nanotubes via in situ emulsion polymerization (2016, background): “Molecular assembly has been reported to tether polymer brushes on organic, polymeric, and inorganic substrates such as poly(ethyleneterephthalate) [16], poly(vinyl chloride) [17], Al2O3 [18], Fe3O4 [19], ZnO [20], and carbon black [21].”