Dynamics of silicon metabolism and silicon isotopic discrimination in a marine diatomas a function of pCO2

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Effects of changing pCO2 and phosphate availability on domoic acid production and physiology of the marine harmful bloom diatom Pseudo‐nitzschia multiseries (2011, result): “1979.”
Environmental controls on coccolithophore calcification (2012, background): “Milligan et al. (2004) showed a small increase in the rate of dissolution of silica from diatom frustules with increasing CO2 concentration in seawater; the mechanism of this effect is unknown.”
A Review of the Stable Isotope Bio-geochemistry of the Global Silicon Cycle and Its Associated Trace Elements (2018, background): “Diatoms preferentially take up the lighter isotopes of Si during silicification (De La Rocha et al., 1997; Milligan, 2004; Sutton et al., 2013), resulting in a higher δ30SiDSi signature in surface ocean DSi (Figure 1).”
Ocean acidification enhances the growth rate of larger diatoms (2014, background): “…less attention since availability of silicate is not directly affected by OA; however, growing evidence suggests that OA may alter silicification (Milligan et al. 2004; Herve et al. 2012), growth rates, elemental composition, and productivity of marine diatoms (Burkhardt et al. 1999, 2001;…”