Open-Structured Vanadium Dioxide as an Intercalation Host for Zn Ions: Investigation by First-Principles Calculation and Experiments

By Jae-Sang Park, J. Jo, Y. Aniskevich, A. Bakavets, G. Ragoisha, E. Streltsov, Jongsoon Kim, Seung‐Taek Myung. Chemistry of Materials, 2018

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Zinc-ion batteries are emerging as next-generation rechargeable batteries that can operate in aqueous electrolytes. We first examine the feasibility of open-structured VO2(B) as a Zn2+ intercalation host. A bond-valence sum energy map predicts that four Zn2+-ion sites (ZnC, ZnA1, ZnA2, and ZnC′) can exist in the structure. Using first-principles calculations, we verified that 0.5 mol of Zn2+ ions can be reversibly (de)intercalated with an average voltage of ∼0.61 V (vs Zn2+/Zn), which is comparable with the experimental results. The specific capacity of VO2(B) at 50 mA g–1 is maintained up to ∼365 mAh g–1 corresponding to the storage capacity of ∼0.57 mol of Zn2+ ions in the framework of VO2(B), and its redox reaction occurs at ∼0.61 V. The high capacity is maintained for 200 cycles, with capacity retention of 80% (288 mAh g–1). Moreover, the capacity delivered by the VO2(B) electrode is stable even with cycling at a rate of 5C (1750 mA g–1) at approximately 110 mAh g–1. This high-power capability of VO2 ...

Subfields: Electrical and Electronic Engineering, Polymers and Plastics

View Paper: https://www.semanticscholar.org/paper/32091d46c8c1fdca69b56167a7a08afb6bf93a52