A LiCl-mediated Br/Mg exchange reaction for the preparation of functionalized aryl- and heteroarylmagnesium compounds from organic bromides.

By A. Krasovskiy, P. Knochel. Angewandte Chemie, 2004

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Discovery and Synthesis of a Phosphoramidate Prodrug of a Pyrrolo[2,1-f][triazin-4-amino] Adenine C-Nucleoside (GS-5734) for the Treatment of Ebola and Emerging Viruses (2017, methodology): “base which enabled a more facile metal-halogen exchange compatible with i-PrMgCl•LiCl complex.(39) Treatment with PhMgCl and TMSCl provided 6N protection to remove the acidic”