Highly Efficient “Click” Functionalization of Poly(3-azidopropyl methacrylate) Prepared by ATRP

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Cylindrical molecular brushes: Synthesis, characterization, and properties (2008, methodology): “By employing highly efficient copper(I)-catalyzed azide–alkyne coupling reactions [119,120] commonly classified as a form of ‘‘click chemistry’’ [121] postpolymerization modification reactions have been observed to proceed to high conversion [122–126].”
Photomediated controlled radical polymerization (2016, positive): “ATRP and CuAAC processes are both based on a similar Cu(I) catalytic system, their sequential or simultaneous combinations provide versatile routes for the construction of a variety of complex and functional macromolecular structures from heterofunctional molecules.[292-295] The mechanistic combinat”