On the mechanisms by which the charged droplets produced by electrospray lead to gas phase ions

By P. Kebarle, M. Peschke. 2000

301 citations recorded by the source corpus.

Subfields: Electrical and Electronic Engineering, Materials Chemistry, Spectroscopy

View Paper: https://www.semanticscholar.org/paper/2c138a0156de09eee26f21b33b65a1a130a8b5a8

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Citations in the corpus

• An extractive electrospray ionization time-of-flight mass spectrometer (EESI-TOF) for online measurement of atmospheric aerosol particles (2019, unknown): “During the rapid evaporation of the solvent from the electrospray droplets, surface charge is concentrated and ions are ejected into the gas phase, presumably by the Coulomb explosion mechanism (Kebarle and Peschke, 2000).”
• Practical implications of some recent studies in electrospray ionization fundamentals. (2001, background): “In ESI, analyte charging in the gas phase generally occurs through gas-phase proton-transfer reactions (Zhou & Hamburger, 1995; Yen, Charles, & Voyksner, 1996; Kebarle & Peschke, 1999; Amad et al., 2000).”