The effect of pressure, temperature, oxygen fugacity and composition on partitioning of nickel and cobalt between liquid Fe-Ni-S alloy and liquid silicate: implications for the earth’s core formation

By Jie Li, C. Agee. 2001

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Nitrogen solubility in molten metal and silicate at high pressure and temperature (2012, background): “These durations are sufficient to achieve equilibrium between silicate and metallic liquids in the temperature range of the present experiments (Thibault and Walter, 1995; Li and Agee, 2001).”
Magma oceans in the inner solar system (2012, methodology): “This model may be too simple: Physical and chemical arguments for metal-silicate equilibrium in droplets raining through the magma ocean appear convincing (Li & Agee 2001, Rubie et al. 2003), and equilibration may therefore occur over a wide range of pressures.”
Heterogeneous accretion, composition and core–mantle differentiation of the Earth (2011, background): “% S on the metal–silicate partitioning of the elements under consideration is insignificant (Li and Agee, 2001; Mann et al., 2009; Righter, 2003) and S is not included in the mass balance; however, 2 wt.”