Fundamental and solutions of microcrack in Ni-rich layered oxide cathode materials of lithium-ion batteries

By Shouyi Yin, W. Deng, Jun Chen, X. Gao, Guoqiang Zou, Hong-shuai Hou, Xiaobo Ji. 2021

452 citations recorded by the source corpus.

Abstract Ni-rich layered transition metal oxide is one of the most promising cathode materials for the next generation lithium-based automotive batteries due to its excellent electrochemical performances. Nevertheless, its further applications are capped by the structural/interfacial instability during the prolonged charging/discharging, leading to severe performance fading and serious safety concerns. Here, we provide a comprehensive review about challenges and solutions to modify Ni-rich layered cathodes specifically for microcrack failure. Firstly, the mechanism of microcrack formation and evolution are concluded thoroughly. Secondly, recent advances in stabilizing the structure/interface of Ni-rich cathodes are summarized such as surface coating, cation/anion doping, composition tailoring, morphology engineering and electrolytes optimization. Furthermore, strategies to mitigate the microcrack and then boost the electrochemical performance of Ni-rich cathodes at the chemical & mechanical engineering level are presented. More importantly, outlook and perspectives to facilitate the practical application of Ni-rich layered cathodes toward electrical vehicle application are provided as well.

Subfields: Electrical and Electronic Engineering, Electronic, Optical and Magnetic Materials

View Paper: https://www.semanticscholar.org/paper/22a0b6f0c06d6c9d5fc626dc5896e101f90edd88

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