Synthesis and characterization of (Ba, Sr)Fe2(As, P)2 iron pnictide superconductors

By S. Kasahara, T. Shibauchi, K. Hashimoto, K. Ikada, S. Tonegawa, R. Okazaki, Hitoshi Ikeda, H. Takeya, Ken-Ichi Hirata, T. Terashima and 1 more. 2009

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Abstract We prepared polycrystalline samples with nominal compositions of (Ba 0.5 Sr 0.5 )Fe 2 (As 1− x P x ) 2 ( x  = 0. 2, 0.3, 0.35, 0.4, 0.5, 0.6). Nearly single-phase samples were successfully obtained. Rietveld refinements of the powder XRD data revealed that the cell volume was gradually reduced with increasing the P content x . Comparing with the reported data for P-substituted Ba122 (Ba122:P) and Sr122 (Sr122:P), the P-substituted (BaSr)122 exhibited intermediate structural properties. The structure of the Fe 2 (As, P) 2 block was almost identical regardless of different alkaline earth elements. The sample with x  = 0.4 showed the highest T c of 29 K, being nearly identical to those of Ba122:P and Sr122:P.

Subfields: Electronic, Optical and Magnetic Materials, Oncology

View Paper: https://www.semanticscholar.org/paper/1e82274a866df4fa3738dbdc6772d4340fda0b61

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In Electronic, Optical and Magnetic Materials

  1. G. Stewart

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