Novel Two-Dimensional Network Constructed from Polyoxomolybdate Chains Linked through Copper−Organonitrogen Coordination Polymer Chains: Hydrothermal Synthesis and Structure of…

By Ying Lu, Yan Xu, E. Wang, Jian Lü, Andy Hu, Lin Xu. 2004

144 citations recorded by the source corpus.

A novel compound, [H2bpy][Cu(4,4‘-bpy)]2[HPCuMo11O39] (1), has been prepared under mild hydrothermal conditions and has been structurally characterized by single-crystal X-ray diffraction. Compound 1 exhibits a novel two-dimensional network constructed from the interconnecting of polyoxomolybdate chains, {HPCuMo11O39}n4n-, and transition metal coordination polymer chains, {Cu(4,4‘-bpy)}nn+. It is the first example of a two-dimensional structure formed by a polyoxomolybdate chain through the linkage of a transition metal coordination polymer chain.

Subfields: Inorganic Chemistry, Materials Chemistry

View Paper: https://www.semanticscholar.org/paper/1db255253d5e696542af906315a44a478473ada4