Nickel, Manganese, and Cobalt Dissolution from Ni-Rich NMC and Their Effects on NMC622-Graphite Cells
By Roland Jung, Fabian Linsenmann, Rowena Thomas, J. Wandt, S. Solchenbach, F. Maglia, C. Stinner, M. Tromp, H. Gasteiger. Journal of the Electrochemical Society, 2019
292 citations recorded by the source corpus.
Transition metal dissolution from the cathode active material and its deposition on the anode causes significant cell aging, studied most intensively for manganese. Owing to their higher specific energy, the current focus is shifting towards nickel-rich layered LiNixMnyCozO2 (NMC, x + y + z = 1) with x > 0.5, so that the effect of Ni dissolution on cell degradation needs to be understood. This study investigates the dissolution of transition metals from a NMC622 cathode and their subsequent deposition on a graphite anode using operando X-ray absorption spectroscopy. We show that in NMC622-graphite cells transition metals dissolve nearly stoichiometrically at potentials > 4.6 V, highlighting the significance of investigating Ni dissolution/deposition. Using NMC622-graphite full-cells with electrolyte containing the bis(trifluoromethane) sulfonimide (TFSI) salts of either Ni, Mn, or Co, we compare the detrimental impact of these metals on cell performance. Using in-situ and ex-situ XRD, we show that the aging mechanism induced by all three metals is the loss of cycleable lithium in the solid electrolyte interface (SEI) of the graphite. This loss is larger in magnitude when Mn is present in the electrolyte compared to Ni and Co, which we ascribe to a higher activity of deposited Mn towards SEI decomposition in comparison to Ni and Co. (C) The Author(s) 2019. Published by ECS.
Subfields: Automotive Engineering, Electrical and Electronic Engineering
View Paper: https://www.semanticscholar.org/paper/1c3f123cd3aca67e9df6bf840ab9fe79d65cbaf6
How researchers see this paper
The researchers whose trusted networks rank it highest, strongest advocate first. Every researcher gets a different order.
In Automotive Engineering
In Electrical and Electronic Engineering
Citations in the corpus
- A review of gas evolution in lithium ion batteries (2020, background): “the increase in SEI formation has also been observed from manganese dissolution from NMC electrode [50].”