Lithium storage in a metal organic framework with diamondoid topology – a case study on metal formates

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The Chemistry and Applications of Metal-Organic Frameworks (2013, background): “2 cm (2)/V·s (27) Lithium storage capacity (after 60 cycles) Zn3(HCOO)6 560 mAh/g (28) Earliest report Catalysis by a MOF Cd(BPy)2(NO3)2 1994 (29)”
Metal-organic frameworks and their derived materials for electrochemical energy storage and conversion: Promises and challenges (2017, background): “2017;3 : eaap9252 1 December 2017 via possible conversion and/or alloying reactions at low potential, whereas detailed investigations would be necessary to reveal the mechanism (23, 24).”
Metal organic frameworks for energy storage and conversion (2016, unknown): “– – [74] 60 560 [75] 60 410 [75] 60 510 [75] 100 650 [76] 5 304 [78]”
MOFs and COFs for Batteries and Supercapacitors (2019, methodology): “(1)Zn4O(BTB)2(DEF)m(H2O)n + e + Li + → Zn + Li2O (2)DEF + H2O + e + Li + → Li2(DEF) + LiOH Another Zn-based MOF [105], Zn3(HCOO)6, with diamondoid structure was also applied as the anode material and achieved a reversible capacity of 560 mA h g−1 after 60 cycles at 60 mA g−1.”