Conformational changes and phase transformation mechanisms in PVDF solution-cast films

By A. Salimi, A. Yousefi. 2004

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Effect of filler size and concentration on the structure and properties of poly(vinylidene fluoride)/BaTiO3 nanocomposites (2012, background): “The presence of the β-phase is identified by infrared spectroscopy mainly through the characteristic absorption band at 840 cm and the α-PVDF by the bands at 765, 795, 855 and 976 cm [3,21].”
Fabrication and characterization of 3D printed BaTiO3/PVDF nanocomposites (2018, background): “Due to its unique chain conformation in crystal unit cell and its high highest remnant polarization, b-phase has attracted the most attention among the PVDF phases for its enhanced piezoelectric and pyroelectric applications among polymers.(3) On the other side, piezoelectric ceramics have been util”
Effect of annealing on phase transition in poly(vinylidene fluoride) films prepared using polar solvent (2011, background): “F bond in the PVDF molecular chain and reduce the energy barrier for forming the more expanded all trans conformation while solvents with a lower dipole moment always favors alternate trans and gauch conformation (Salimi and Yousefi 2004; Chen et al 2007).”