Oxide nanoparticle reservoirs for storage and prolonged release of the corrosion inhibitors

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Review of electrochemical properties of hybrid coating systems on Mg with plasma electrolytic oxidation process as pretreatment (2019, background): “Also, it has been evidenced that cerium ions in the form of mixed oxide nanoparticles (such as ZrO2/CeO2) can act as nano-capsules for slow release of cerium ions in case of a failure occurred in the coating process [209].”
Green Inhibitors for Corrosion Protection of Metals and Alloys: An Overview (2012, background): “Corrosion inhibition of mild steel in acidic solution by the dyemolecules can be explained on the basis of adsorption on the metal surface, due to the donor-acceptor interaction between π electrons of donor atoms N, O and aromatic rings of inhibitors, and the vacant d-orbitals of iron surface atoms ”
Electrochemical study of inhibitor-containing organic–inorganic hybrid coatings on AA2024 (2009, background): “Very promising approaches for the active corrosion protection of AA2024-T3 by incorporation of corrosion inhibitors into sol–gel coatings have been recently reported [18–26].”