Advanced carbon electrode materials for molecular electrochemistry.

By R. McCreery. Chemical Reviews, 2008

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There is no evidence to support literature claims of direct electron transfer (DET) for native glucose oxidase (GOx) at carbon nanotubes or graphene (2017, background): “electronic structure of the two materials and the consequent difference in the density of states at the Fermi level [61, 62].”
Carbon as Catalyst and Support for Electrochemical Energy Conversion (2014, background): “Carbon nanomaterials and specifically CNTs are widely used in these electrochemical sensors due to their attractive characteristics (high conductivity and sensitivity, good selectivity and reversibility, fast response time, chemical and thermal stability, electronic and optical properties) [215-217]”
Nanodiamond Particles: Properties and Perspectives for Bioapplications (2009, background): “217 , 218 Boron is by far the most widely used dopant to produce conducting diamond electrodes.”
Hybrid carbon based nanomaterials for electrochemical detection of biomolecules (2017, background): “For Fe(CN)6(4) /3 this could be expected as it is surface sensitive redox couple [252].”