The conversion technology of fly ash into zeolites

By M. Wdowin, M. Franus, R. Panek, L. Badura, W. Franus. Clean Technologies and Environmental Policy, 2014

217 citations recorded by the source corpus.

This paper presents a sub-pilot scale process of synthesis of Na-P1 zeolite from the coal fly ash. After establishing the appropriate synthesis conditions (20 kg of fly ash, 12 kg of NaOH, 90 dm3 of water, the reaction temperature: 80 °C and reaction time: 36 h), the high-purity (81 wt%) Na-P1 zeolite product was obtained. Its chemical, mineralogical, and textural properties were determined (by means of XRD, XRF, SEM–EDS and ASAP 2020). The synthesized material has a specific BET surface area (88 m2/g) c.a. six times higher than the fly ash from which it has been derived (15 m2/g). The pore-size distribution indicates a mesoporous character of the obtained zeolite, with the following pores size contents: micropores (2.76 %), mesopores (61.81 %), and macropores (35.43 %). The presented technological/production line is fully automated and allows to regulate the conditions of the synthesis process, therefore different types of zeolite materials (including: Na-X, Linde-A, and Na-P1) can be obtained using the same equipment.

Subfields: Inorganic Chemistry, Materials Chemistry

View Paper: https://www.semanticscholar.org/paper/0ba204c24cc9f987586aefc1f928ce769d9582ae

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  1. L. Bandura
  2. M. Smol
  3. G. Józefaciuk
  4. W. Franus
  5. J. Kulczycka
  6. M. Franus
  7. A. Avdiushchenko

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