Thermal decomposition and burning behavior of cellulose treated with ethyl ester phosphoramidates: effect of alkyl substituent on nitrogen atom.

By Sabyasachi Gaan, P. Rupper, V. Salimova, M. Heuberger, S. Rabe, F. Vogel. 2009

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Flame retardant challenges for textiles and fibres: New chemistry versus innovatory solutions (2011, background): “In a not-unrelated paper, work by the Swiss research team [52] has investigated the”
Functionalization of cellulose fibres with DOPO-polysilsesquioxane flame retardant nanocoating (2015, background): “…the effective protection of cellulose, flame retardants should prevent levoglucosan formation and accelerate the formation of a protective char layer by catalyzing the dehydration of cellulose macromolecules in the condensed phase (Alongi et al. 2013a, b; Horrocks and Price 2001; Gaan et al. 2009).”
Synthesis of a novel PEPA-substituted polyphosphoramide with high char residues and its performance as an intumescent flame retardant for epoxy resins (2015, background): “Moreover, it was reported that phosphoramide structure could be more effective than phosphate structure in promoting the char formation and reducing the pyrolysis gases [39].”