Odyssey of Multivalent Cathode Materials: Open Questions and Future Challenges.

By P. Canepa, G. Sai Gautam, Daniel C. Hannah, R. Malik, Miao Liu, K. Gallagher, Kristin A. Persson, Gerbrand Ceder. Chemical Reviews, 2017

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Emerging rechargeable aqueous aluminum ion battery: Status, challenges, and outlooks (2020, neutral): “The speci ﬁ c volumetric capacity of an Al anode is up to 8046 mAh cm (cid:2) 3 , close to 4 times higher compared with Li (2062mAh cm (cid:2) 3 ), with its gravimetric capacity (2980 mAh g (cid:2) 1 ) comparable to that of Li metal (3860 mAh g (cid:2) 1 ) [5].”
Vanadium Oxide Pillared by Interlayer Mg2+ Ions and Water as Ultralong-Life Cathodes for Magnesium-Ion Batteries (2019, background): “stitutes benefitting from the advantages of good safety, low cost, and high energy density.(4,5) Among them, magnesium (Mg) batteries have been regarded as the most promising candidate.”
Directing Mg-Storage Chemistry in Organic Polymers toward High-Energy Mg Batteries (2019, background): “A major challenge for realizing viable Mg batteries is the hunt for high-performance cathodematerials that are chemically compatiblewith electrolytes in which highly reversible Mg deposition and stripping occur.(2,3) Magnesium ion has the radius of a Li ion but double the positive charge, and hence ”
Lithium ion, lithium metal, and alternative rechargeable battery technologies: the odyssey for high energy density (2017, background): “magnesium batteries [25, 26, 144, 145], potassium-ion batteries [146, 147], and calcium (-ion) batteries [25, 148, 149].”